Showing posts with label damaged groundwater. Show all posts
Showing posts with label damaged groundwater. Show all posts

Sunday, February 28, 2010

Diagnostic Monitoring of Biogeochemical Interactions of a Shallow Aquifer in Response to a CO2 Leak

A grant to watch -

http://cfpub.epa.gov/ncer_abstracts/index.cfm/fuseaction/display.abstractDetail/abstract/9053/report/0

EPA Grant Number: R834503
Title: Diagnostic Monitoring of Biogeochemical Interactions of a Shallow Aquifer in Response to a CO2 Leak
Institution: Columbia University in the City of New York
Project Period: September 1, 2009 through August 31, 2012
Project Amount: $899,882
RFA: Integrated Design, Modeling, and Monitoring of Geologic Sequestration of Anthropogenic Carbon Dioxide to Safeguard Sources of Drinking Water (2009)
Research Category: Drinking Water

Objective:
CO2 injection into deep geological formations capped by low permeability formations is one of the most promising alternatives for mitigation of anthropogenic climate change. Several deep pilot and demonstration projects are underway. However, the upward leakage of CO2 or mobilized brines through the cap rock could lead to vulnerability of shallow, overlying drinking water aquifers. Elevated levels of dissolved CO2 might affect microbial community dynamics and mobilize natural-radioisotopes, metals, and other non-potable elements and compounds. The proposed research will investigate a shallow potable water aquifer system in sand/clay sequences of the Newark Basin group using laboratory and in situ methods and test how it would respond to a high-level CO2 condition caused by a hypothetical leakage of CO2 from deep injection reservoirs. In particular, we will (1) determine metal release rates as a function of pCO2 and pH under laboratory and field conditions, (2) measure microbial community dynamics as a function of increased acidity and dissolved metal concentrations, (3) determine the role and persistence of microbial communities in the mobilization or immobilization of metallic elements, (4) measure in situ/ex situ mobilization and immobilization of metals under high-level CO2 conditions, (5) determine the extent to which leaked CO2 is geochemically trapped in the aquifer, and (6) develop diagnostic monitoring techniques to advance assessments of groundwater contamination risks and water quality deterioration due to a CO2 leakage event.


Approach:
We will conduct a series of geochemical and microbiological laboratory experiments using rock and water samples extracted from a shallow aquifer. We will also add CO2 (pCO2 up to 5 bars) to local groundwater, re-inject it into the aquifer, and then sample and monitor the elevated-CO2 aquifer water in a series of in situ push-pull and forced-gradient experiments.

Expected Results:
Results from these coupled laboratory and field experiments will greatly improve our understanding of the geochemical and microbiological reactions under low pH - high CO2 stress. We anticipate that this research will: (1) provide criteria for site selection for geological CO2 sequestration, (2) identify aquifers that would be least vulnerable to risks of CO2 leakage and subsequent contamination, and (3) provide a small number of diagnostic testing parameters that may be used in other potable aquifer systems associated with deep CO2 injection.

Supplemental Keywords:
sequestration, pollution prevention, metals, pathogens, groundwater,

Thursday, May 28, 2009

Freshwater Aquifer Risk - water ,our most precious resource -at risk

The information on this page comes from the Ohio EPA - Division of Drinking and Ground Waters- click here to be taken to their site


Sole Source Aquifers -

Greenville, Ohio is the proposed site of one of the 7 large-scale CO2 Sequestration Demonstration projects - to pump 1 M tons of CO2 into the saline aquifer - AND it is one of the areas that sits on top of a Sole Source Aquifer - an even greater reason consider the risks involved with burying supercritical CO2 underground FOREVER!

One of the most important aquifers, in regards to contamination is a Sole Source Aquifer. The contamination of any aquifer, not just sole source aquifers, greatly effects surrounding communities.

The Great Miami Aquifer, that Greenville is part of, is one of the nation's LARGEST drinking water aquifers.

"U.S. EPA defines a Sole Source Aquifer (SSA) as an aquifer that supplies at least 50 percent of the drinking water consumed in the area overlying the aquifer. These areas may have no alternative drinking water source(s) that could physically, legally and economically supply all those who depend on the aquifer for drinking water.

The Sole Source Aquifer designation protects an area's ground water resource by requiring U.S. EPA to review certain proposed projects within the designated area. All proposed projects receiving federal funds are subject to review to ensure that they do not endanger the water source."

"For convenience, all designated sole or principal source aquifers are referred to as "sole source aquifers" (SSA). " The designation of an aquifer as a sole source aquifer "provides EPA with the authority to review federal financially assisted projects planned for the area to determine their potential for contaminating the aquifer. Federally funded projects reviewed by EPA under the SSA program may include, but not be limited to, highway improvements and new road construction, public water supply wells, transmission lines, wastewater treatment facilities, construction projects involving disposal of storm water, and agricultural projects involving management of animal waste."
Greater Miami Sole Source Aquifer
http://www.epa.state.oh.us/ddagw/Documents/greatmiami-ssa.pdf

The Great Miami Buried Valley Aquifer (GMBVA) is an extensive sand and gravel aquifer that extends in a southwesterly direction from Indian Lake, north of Dayton, Ohio, to the Ohio River, generally following the course of the Great Miami River.

The GMBVA is classified by the United States EPA as a "Sole Source Aquifer" which applies only to aquifers serving as the sole or principal source of drinking water for the petitioned area and which, if contaminated, would create a significant hazard to public health. For this reason all Federal financially assisted projects constructed in the Great Miami River Valley and its principal recharge zone are subject to USEPA review to insure that the projects are designed and constructed in a manner that does not a significant hazard to public health.(Source http://www.gwconsortium.org/GMBVA.html)



Below is a VERY informative link to a document entitled: Hydrology, Aquifers, Geology - and it talks about how aquifers are contaminated.In order to understand the critical role groundwater plays to society and the importance of removing contamination, we must first understand the role of hydrology.

Hydrology is the branch of geology that deals with the occurance, distribution and effect of groundwater. Contrary to popular belief, groundwater is typically NOT FOUND underground in a body of water similar to a lake or river. It is most often contained in the cavities, pores and voids interspersed among rocks, gravel, sand and soil in the earth's subsurface. When useful quantities of extractable water are found in these geological formations the area is known as an aquifer - "water bearer".

Additionally, this site references The Mound and the Fernald Plants and their impact on The Great Miami Aquifer and the need to keep our aquifers safe by implementing independent, "rigorous monitoring regimes" that are "adequately funded and free of the bias of the DOE - an agency that wants to downplay problems and gloss over errors of the past."

http://www.ananuclear.org/Portals/0/documents/Water%20Reportwaterreporthydrology.pdf


http://oh.water.usgs.gov/miam/Ground_Water.html

Transport of agricultural chemicals in five watersheds across the U.S.

Monday, May 11, 2009

King Coal's Latest Con Job


From the web site - http://www.counterpunch.org/blair01232007.html

January 23, 2007

King Coal's Latest Con Job

Clean Coal is Not Clean

By JOHN BLAIR

Proponents of Integrated Gasification Combined Cycle (IGCC) technology like that Duke and Vectren desire to use at Edwardsport, Indiana, loudly proclaim that IGCC is the answer to global warming since the technology makes its easier to capture carbon dioxide. Once captured, their pitch is that it can be "sequestered" for thousands of years in deep geological formations. Out of sight, out of mind.

In December 2006, the US Department of Energy finally admitted in a supplement to an Environmental Impact Statement (EIS) for an IGCC plant in Pennsylvania that, "DOE has considered the potential to reduce project CO2 emissions using geologic sequestration. This is not a reasonable option because sequestration technology is not sufficiently mature to be implemented at production scale during the demonstration period for the proposed facilities."

This admission is consistent with most recent research done by government and private sources as it relates to sequestration. In fact, most recent research tells a story that makes the whole idea of sequestration questionable, at best, and perhaps even dangerous for those who may live near the areas where CO2 is dumped underground.

Three areas of concern have emerged in recent studies.

1. CO2 injected near earthquake faults like the region of SW Indiana which is in the New Madrid fault zone, may actually increase the potential for earthquakes due to CO2's ability to lubricate geologic plates, making it easier for them to move when subjected to pressure from beneath the earth's surface.

2. Injection of CO2 can ultimately damage groundwater used for drinking by a chemical conversion when the CO2 is injected causing an increase in acidity which leaches dangerous chemicals like metals out of the formation. Those contaminants often find their way to groundwater. Such a chemical conversion could render entire aquifers unusable as drinking water which people depend upon.

3. Huge financial and energy investment in sequestration. Most of the debate about IGCC has evolved around whether it is possible to convert coal to a synthesis gas in a manner that can be used to generate electricity more cleanly than conventional technology called pulverized coal. The real reason utilities are seeking to build these plants is to capture enormous federal and state taxpayer funded subsidies. For instance, Duke and Vectren were recently awarded more than $133 million in federal tax credits to build their costly and dirty plant.

This wrongly labeled "clean coal" has proven to be somewhat cleaner from an air pollution standpoint than pulverized coal but missing from the debate has been a real assessment of what to do with the captured chemicals that are by-products of the process, what the cost of actually building and operating these facilities will be on a commercial scale, how much of the energy produced will be required to run the sophisticated chemical processes required thus reducing the overall efficiency of the plants and what is the actual cost of capturing the CO2 and permanently storing it in some underground geological formation.

As it currently stands, not a single one of these IGCC proposals addresses any of these issues in any great detail. Not only that, but most IGCC proposals are not even promising carbon capture, let alone sequestration.

Add to that the fact that the costs of building proposed IGCC plants has completely gone through the roof. In Minnesota, government documents have recently revealed the cost of Excelsior's Mesaba IGCC has gone to at least $2.155 billion for a 603 MW facility. That's a whopping $3.5 million per megawatt, higher than projected cost for nuclear plants these days. It is also true in Indiana where Duke Energy president, Jim Rogers told the media a couple of months ago that the cost of their Edwardsport IGCC plant had increased in cost to build from $1.3 billion in early 2006 to what is now in excess of "$2 billion" for 630 megawatts. That is a per MW cost of $3.17 million and rising. Neither of these facilities have projected the cost to capture and sequester carbon which most estimates suggest will be at least another 50% in construction costs and a big unknown as to what it will cost to actually capture and store the CO2 in operational costs.

Using the conservative 50% figure, the cost of the Edwardsport plant to construct could rise to $4.75 billion or more than $7.5 million/MW. Contrast that with the ill fated Marble Hill Nuclear plant which was forced to stop construction in 1984 due to its rising costs. PSI (now Duke) said originally in 1973 that Marble Hill would cost $700 million for 2,260 MW ($309,000/MW). When it finally went through hearings in 1977, the cost had doubled to $1.4 billion ($619,000/MW). When the state of Indiana forced PSI to stop construction by telling them they would not guarantee that they would allow the plant to be placed into PSI's rate base, the construction costs had risen to $10 billion ($ 4.4 million/MW).

The comparison with IGCC technology and nukes is valid. Both were risky ventures that required significant government support to be economically feasible at all. Both stood to make their sponsors extremely high profits since they are guaranteed a profit based on their level of investment. (With Marble Hill the allowed rate of return was about 8%, now Duke and Vectren seek a 12% rate of return.)

When the cost of building coal plants rises to a certain level, ALL alternatives should be on the table. Ecological destruction when mined, multiple health problems when burned and contaminating our drinking water when the waste is dumped into aquifers and streams are abundant reasons why alternatives to coal should be pursued.

Who can list a single "Coal community" as prosperous? Indeed, it is the opposite. Coal is the bane of those forced to live near coal, not our economic salvation.

John Blair is president of the environment health advocacy group, Valley Watch and earned a Pulitzer Prize for news Photography in 1978. He can be reached at: Ecoserve1@aol.com